Structure and magnetism of new hybrid cobalt hydroxide materials built from decorated brucite layers
Dalton Transactions, ISSN: 1477-9226, Vol: 40, Issue: 12, Page: 2983-2994
2011
- 16Citations
- 22Captures
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Article Description
The structure, synthesis and magnetic properties of three new complex cobalt hydroxyl oxalates are presented, showing a modification of the 2-D double layer hydroxide structure. Co(OH)(ox) (pip) [ox = oxalate, CO; pip = piperazine, CNH] (1), is essentially built from brucite-like layers with a one ninth depletion of the octahedral sites and a preservation of a trigonal crystallographic symmetry. ACo(OH) (ox)Br(HO) [A = Na (2), K (3)] are similarly composed of a brucite-like layer with three nineteenths depletion of octahedral sites, again preserving a trigonal symmetry. Both 2 and 3 show a small degree of structural disorder within the framework. All of these compounds have alternating layers of a mineral-like metal hydroxide structure and a metal oxalate coordination network, with the depletion in the hydroxyl layers being templated by the coordination network. Magnetic studies of 1 reveal a metamagnetic character, with the onset of an antiferromagnetic phase below T = 23.5 K (H = 0 G), and a first order antiferromagnet to metamagnet transition at H = 500-1000 G (T = 20-6 K). Compound 3 shows a more conventional ferrimagnetic ordering below 33(±1) K with a small coercive field of 107(±5) G at 10 K. © The Royal Society of Chemistry 2011.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79952665815&origin=inward; http://dx.doi.org/10.1039/c0dt01007c; http://www.ncbi.nlm.nih.gov/pubmed/21327226; https://xlink.rsc.org/?DOI=c0dt01007c; https://dx.doi.org/10.1039/c0dt01007c; https://pubs.rsc.org/en/content/articlelanding/2011/dt/c0dt01007c
Royal Society of Chemistry (RSC)
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