Synthesis of hybrid dendritic molecules with diazaphospholidine oxide grafted at the surface of octavinylsilsesquioxane (OVS)
Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 9, Issue: 4, Page: 1189-1200
2011
- 9Citations
- 16Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
A range of dendritic molecules was made using the monodentate SEMI-ESPHOS phosphine oxide ligand, which was derivatised with a series of functional groups including bromide, vinyl, allyl and terminal alkyne. Several methods to attach the resulting precursors onto octavinylsilsesquioxane (OVS), ranging from hydrosilylation, Suzuki, Heck, Grubbs or Sonogashira coupling reactions, have been investigated. Cross-metathesis of SEMI-ESPHOS oxide dendrons containing vinyl end groups with OVS catalyzed by Grubbs' catalyst was proven to be effective in the formation of precursors for dendritic molecules based on OVS. © 2011 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79551670179&origin=inward; http://dx.doi.org/10.1039/c0ob00297f; http://www.ncbi.nlm.nih.gov/pubmed/21152659; http://xlink.rsc.org/?DOI=C0OB00297F; http://pubs.rsc.org/en/content/articlepdf/2011/OB/C0OB00297F; https://xlink.rsc.org/?DOI=C0OB00297F; https://dx.doi.org/10.1039/c0ob00297f; https://pubs.rsc.org/en/content/articlelanding/2011/ob/c0ob00297f
Royal Society of Chemistry (RSC)
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