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Synthesis of the core ring system of the stemona alkaloids by cascade condensation, cyclization, intramolecular cycloaddition

Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 8, Issue: 20, Page: 4530-4532
2010
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Condensation of an aldehyde with an α-amino-ester, followed by a tandem process involving cyclization to a seven-membered ring, deprotonation to an intermediate azomethine ylide and intramolecular dipolar cycloaddition gave tricyclic products related to stenine and neostenine. © 2010 The Royal Society of Chemistry.

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