Colorimetric detection of achiral anions and chiral carboxylates by a chiral thiourea-phthalimide dyad
Photochemical and Photobiological Sciences, ISSN: 1474-9092, Vol: 9, Issue: 10, Page: 1385-1390
2010
- 13Citations
- 13Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations13
- Citation Indexes13
- CrossRef13
- 12
- Captures13
- Readers13
- 13
Article Description
The chiral chemosensor 1, based on a thiourea-activated phthalimide, is available by four reaction steps from 4-nitrophthalimide. 1 detects fluoride, chloride, acetate, and dihydrogen phosphate anions by changes in UV-vis absorption. Fluoride in excess induces deprotonation whereas the other anions show only complex formation in the ground state. H-NMR studies confirm the formation of these H-bonded complexes and the fluoride-induced receptor deprotonation in the recognition process. Moderate chiral recognition was observed for sodium d/l-lactate with K(d)/K(l) = 1.93. © 2010 The Royal Society of Chemistry and Owner Societies.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79951607120&origin=inward; http://dx.doi.org/10.1039/c0pp00175a; http://www.ncbi.nlm.nih.gov/pubmed/20820676; https://link.springer.com/10.1039/c0pp00175a; https://dx.doi.org/10.1039/c0pp00175a; https://link.springer.com/article/10.1039/c0pp00175a
Springer Science and Business Media LLC
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