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Pd(0)/Au(i) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(i)-complexes

Chemical Communications, ISSN: 1364-548X, Vol: 47, Issue: 18, Page: 5172-5174
2011
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A Pd(ii)-catalyzed homo-coupling of Au(i)-aryls is reported. The reaction is driven by a Pd(0)/Au(i) redox reaction that generates a gold mirror and Pd(ii), and illustrates one of the challenges for developing dual catalytic Au-Pd systems. © The Royal Society of Chemistry 2011.

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