Enclathration of bases by a fluorenyl host: Structure, stability and selectivity
New Journal of Chemistry, ISSN: 1369-9261, Vol: 35, Issue: 7, Page: 1556-1561
2011
- 6Citations
- 1Captures
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Article Description
The host compound 9,9′-(1,4-phenylene)-bis-(fluoren-9-ol) forms inclusion compounds with pyridine, the isomers of picoline and morpholine. The structures of the inclusion compounds are stabilised by (Host)O- H⋯N(Guest) hydrogen bonds. Unusually, the structure of the host containing 4-picoline and morpholine displays both cis- and trans-conformation. The enthalpy of enclathration of these guests was estimated by packed-column chromatography. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
Bibliographic Details
Royal Society of Chemistry (RSC)
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