Straightforward synthesis of 1-alkyl-2-(trifluoromethyl)aziridines starting from 1,1,1-trifluoroacetone
Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 9, Issue: 20, Page: 7217-7223
2011
- 37Citations
- 15Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations37
- Citation Indexes37
- 37
- CrossRef32
- Captures15
- Readers15
- 15
Article Description
An efficient and straightforward approach towards the synthesis of 1-alkyl-2-(trifluoromethyl)aziridines starting from 1,1,1-trifluoroacetone via imination, α-chlorination, hydride reduction and ring closure was developed. In addition, novel primary β-iodo amines were obtained by regioselective ring opening of these 2-(trifluoromethyl)aziridines using alkyl iodides, and their synthetic potential was demonstrated by converting them into novel α-CF -β-phenylethylamines upon treatment with lithium diphenylcuprate. © 2011 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=80053305642&origin=inward; http://dx.doi.org/10.1039/c1ob05813d; http://www.ncbi.nlm.nih.gov/pubmed/21874207; https://xlink.rsc.org/?DOI=c1ob05813d; https://dx.doi.org/10.1039/c1ob05813d; https://pubs.rsc.org/en/content/articlelanding/2011/ob/c1ob05813d
Royal Society of Chemistry (RSC)
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