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Palladium-catalyzed allylic C–H amination of alkenes with N-fluorodibenzenesulfonimide: Water plays an important role

Chemical Communications, ISSN: 1364-548X, Vol: 48, Issue: 16, Page: 2246-2248
2012
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A new palladium-catalyzed highly regioselective allylic C–H amination of alkenes with NFSI in the presence of a catalytic amount of water was developed and successfully expanded to Selectfluor-mediated palladium-catalyzed aminations of alkenes with N-tosylcarbamates in water at room temperature. © 2012 Royal Society of Chemistry.

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