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Unexpected formation of the nickel seco-tribenzoporphyrazine with a tribenzotetraazachlorin-type absorption spectrum

Chemical Communications, ISSN: 1364-548X, Vol: 48, Issue: 30, Page: 3650-3652
2012
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Article Description

Minor products in the reaction between substituted 1,3-diiminoisoindolines and 2,5-diamino-3,4-dicyanothiophene were identified as the nickel seco-tribenzoporphyrazines 4 and 5, which have been characterized by UV-vis, MCD, NMR, and mass spectroscopy. Experimentally observed tetraazachlorin-type UV-vis spectra of new seco-tribenzoporphyrazines were explained on the basis of DFT and TDDFT calculations. © 2012 Royal Society of Chemistry.

Bibliographic Details

Nemykin, Victor N; Polshyna, Anna E; Makarova, Elena A; Kobayashi, Nagao; Lukyanets, Evgeny A

Royal Society of Chemistry (RSC)

Chemical Engineering; Materials Science; Chemistry

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