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Unexpected formation of stannolanes and trigonal bipyramidal tin complexes by radical cyclization reaction

Chemical Communications, ISSN: 1364-548X, Vol: 48, Issue: 52, Page: 6592-6594
2012
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Article Description

Optically active stannolanes and trigonal bipyramidal pentacoordinated tin complexes were readily prepared by radical cyclization of N-propargylated chiral aza-Morita-Baylis-Hillman adducts induced by BuSnH. A translocated radical through the cyclization attacked the BuSn group in an S2 manner. © 2012 Royal Society of Chemistry.

Bibliographic Details

Kamimura, Akio; Ishikawa, Shingo; Noguchi, Fumiaki; Moriyama, Takaaki; So, Masahiro; Murafuji, Toshihiro; Uno, Hidemitsu

Royal Society of Chemistry (RSC)

Materials Science; Chemical Engineering; Chemistry

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