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Metal-free arylation of benzene and pyridine promoted by amino-linked nitrogen heterocyclic carbenes

Chemical Communications, ISSN: 1364-548X, Vol: 48, Issue: 53, Page: 6702-6704
2012
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Article Description

An amino-linked nitrogen heterocyclic carbene (amino-NHC), 1-tBu, has been shown to mediate carbon-carbon coupling through the direct C-H functionalization of benzene and pyridine in the absence of a metal catalyst. Using EPR, the first spectroscopic evidence corroborating the single electron transfer mechanism for the metal-free carbon-carbon coupling manifold, as reported by others, is introduced. © 2012 Royal Society of Chemistry.

Bibliographic Details

Chen, Wen-Ching; Hsu, Yu-Chen; Shih, Wei-Chun; Lee, Ching-Yu; Chuang, Wen-Han; Tsai, Yi-Fang; Chen, Peter Ping-Yu; Ong, Tiow-Gan

Royal Society of Chemistry (RSC)

Materials Science; Chemical Engineering; Chemistry

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