Copper-catalyzed trifluoromethylation of aryl- and vinylboronic acids with generation of CF-radicals
Chemical Communications, ISSN: 1364-548X, Vol: 49, Issue: 26, Page: 2628-2630
2013
- 166Citations
- 50Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations166
- Citation Indexes166
- CrossRef166
- 166
- Captures50
- Readers50
- 50
Article Description
The selective trifluoromethylation of aryl- and vinylboronic acids proceeds smoothly with CFSONa (Langlois reagent) in the presence of copper catalysts and t-BuOOH. Therefore, the method relies both on transition metal catalysis and selective radical reactions. Advantageously, the protocol can be performed at room temperature under an air atmosphere and avoids the issue of poor regioselectivity. © The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84874881615&origin=inward; http://dx.doi.org/10.1039/c2cc36554e; http://www.ncbi.nlm.nih.gov/pubmed/23431556; https://xlink.rsc.org/?DOI=c2cc36554e; https://dx.doi.org/10.1039/c2cc36554e; https://pubs.rsc.org/en/content/articlelanding/2013/cc/c2cc36554e
Royal Society of Chemistry (RSC)
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