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Tetrabutylammonium iodide catalyzed allylic sulfonylation of α-methyl styrene derivatives with sulfonylhydrazides

Chemical Communications, ISSN: 1364-548X, Vol: 48, Issue: 100, Page: 12240-12242
2012
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Sulfonyl radicals generated from sulfonylhydrazides by the BuNI-tert-butyl hydroperoxide (TBHP) catalysis system underwent addition to a variety of α-methyl styrene derivatives to give the corresponding allylic sulfones. This selective allylic sulfonylation is metal-free, operationally simple, and environmentally friendly. © 2012 Royal Society of Chemistry.

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