The first examples of thiogermanate anion [GeS(SH)] as a bridging ligand to a lanthanide complex
Dalton Transactions, ISSN: 1477-9234, Vol: 42, Issue: 6, Page: 1961-1964
2013
- 14Citations
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- 1Mentions
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Article Description
Two new lanthanoid thiogermanates [Ln(dien)(μ- η,η-GeS(SH))] {Ln = La(1), Nd(2); dien = diethylenetriamine} were solvothermally synthesized and structurally characterized. Both 1 and 2 represent the first examples of the soft Lewis basic [GeS(SH)] anions as tridentate bridging ligand to hard Lewis acidic Ln ions. Both 1 and 2 exhibit semiconducting properties with absorption band edges of 2.11 eV for 1 and 2.28 eV for 2. The DFT study of 1 indicates a direct band gap with an electronic transfer excitation of S 3p to both Ge 4s and La 5d orbital electrons. © The Royal Society of Chemistry 2013.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84872505062&origin=inward; http://dx.doi.org/10.1039/c2dt32389c; http://www.ncbi.nlm.nih.gov/pubmed/23165504; http://xlink.rsc.org/?DOI=C2DT32389C; http://pubs.rsc.org/en/content/articlepdf/2013/DT/C2DT32389C; https://xlink.rsc.org/?DOI=C2DT32389C; https://dx.doi.org/10.1039/c2dt32389c; https://pubs.rsc.org/en/content/articlelanding/2013/dt/c2dt32389c
Royal Society of Chemistry (RSC)
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