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Nickel-catalyzed C-H direct amination of benzoxazoles with secondary amines

Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 10, Issue: 18, Page: 3715-3720
2012
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Article Description

In this article, a facile, efficient and practical method for Ni-catalyzed direct C-H amination of benzoxazole with secondary amines has been developed. This procedure requires Ni(OAc) ·4H O as catalyst, TBHP as oxidant and acid as the additive. A variety of substituted benzoxazol-2-amines were synthesized in moderate to good yields. © 2012 The Royal Society of Chemistry.

Bibliographic Details

Li, Yaming; Liu, Jin; Xie, Yusheng; Zhang, Rong; Jin, Kun; Wang, Xiuna; Duan, Chunying

Royal Society of Chemistry (RSC)

Biochemistry, Genetics and Molecular Biology; Chemistry

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