Probing the tolerance of cucurbit[7]uril inclusion complexes to small structural changes in the guest
Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 11, Issue: 2, Page: 287-293
2013
- 21Citations
- 30Captures
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Article Description
The binding properties of the cucurbit[7]uril host with three structurally related ferrocene-containing guests, ferrocenyltrimethylammonium, ferrocenylmethyltrimethylammonium and ferrocenylethyltrimethylammonium, have been investigated using H NMR spectroscopy, mass spectrometry, voltammetry and computational methods. The experimental and computational data indicate that the stability of the cucurbit[7]uril inclusion complexes is relatively insensitive to the number of methylenes connecting the trimethylammonium and the ferrocenyl groups, although some of their properties are affected in significant ways. © 2013 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84870886567&origin=inward; http://dx.doi.org/10.1039/c2ob26834e; http://www.ncbi.nlm.nih.gov/pubmed/23175052; http://xlink.rsc.org/?DOI=C2OB26834E; http://pubs.rsc.org/en/content/articlepdf/2013/OB/C2OB26834E; https://xlink.rsc.org/?DOI=C2OB26834E; https://dx.doi.org/10.1039/c2ob26834e; https://pubs.rsc.org/en/content/articlelanding/2013/ob/c2ob26834e
Royal Society of Chemistry (RSC)
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