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A near-infrared and ratiometric fluorescent chemosensor for palladium

Analyst, ISSN: 1364-5528, Vol: 138, Issue: 13, Page: 3667-3672
2013
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A near-infrared chemosensor for palladium based on the Tsuji-Trost reaction was developed. It displayed specific and ratiometric fluorescent responses toward palladium with a distinct color change from green to blue in aqueous media. PEG400 was employed as the reducing agent and palladium ligand instead of water-insoluble triphenylphosphine. The chemosensor's bioimaging potential was demonstrated by in vitro and in vivo experiments.© 2013 The Royal Society of Chemistry.

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