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Quantification of electron transfer rates of different facets on single gold nanoparticles during catalytic reactions

Chemical Communications, ISSN: 1364-548X, Vol: 49, Issue: 45, Page: 5204-5206
2013
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Rayleigh scattering spectra of high-index {730} elongated tetrahexahedral gold nanoparticles and low-index {100}, {110}, and {111} gold nanorods were collected in real time in the reduction of 4-nitrophenol. The high-index facets are capable of accepting electrons seven times faster and emitting electrons two-and-a-half times faster than low-index facets. © 2013 The Royal Society of Chemistry.

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