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Synergistic dual activation catalysis by palladium nanoparticles for epoxide ring opening with phenols

Chemical Communications, ISSN: 1364-548X, Vol: 49, Issue: 52, Page: 5886-5888
2013
  • 49
    Citations
  • 0
    Usage
  • 29
    Captures
  • 0
    Mentions
  • 21
    Social Media
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Metrics Details

  • Citations
    49
  • Captures
    29
  • Social Media
    21
    • Shares, Likes & Comments
      21
      • Facebook
        21

Article Description

Synergistic dual activation catalysis has been devised for epoxide phenolysis wherein palladium nanoparticles induce electrophilic activation via coordination with the epoxide oxygen followed by nucleophilic activation through anion-π interaction with the aromatic ring of the phenol, and water (reaction medium) also renders assistance through ‘epoxide-phenol’ dual activation. © 2013 The Royal Society of Chemistry.

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