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Rhodium catalyzed oxidative coupling of salicylaldehydes with diazabicyclic olefins: A one pot strategy involving aldehyde C–H cleavage and π-allyl chemistry towards the synthesis of fused ring chromanones

Chemical Communications, ISSN: 1364-548X, Vol: 49, Issue: 66, Page: 7349-7351
2013
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An efficient one pot strategy for the synthesis of cyclopentene fused chromanone derivatives through the direct oxidative coupling of salicylaldehydes with bicyclic olefins in the presence of a rhodium–copper catalyst system is described. This is the first report on the ring opening–ring closing of bicyclic hydrazines via metal catalyzed oxidative coupling reaction. © 2013 The Royal Society of Chemistry.

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