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Stepwise addition of difluorocarbene to a transition metal centre

Chemical Communications, ISSN: 1364-548X, Vol: 50, Issue: 9, Page: 1128-1130
2014
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Article Description

The Ruppert–Prakash reagent (MeSiCF) is used to introduce difluorocarbene (CF) and tetrafluoroethylene (TFE) ligands to cobalt(i) metal centres, whereby the TFE ligand is generated via [2+1] cycloaddition between [Co]=CF and CF. © 2013 The Royal Society of Chemistry.

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