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In situ carbon coated LiFePO/C microrods with improved lithium intercalation behavior

Physical Chemistry Chemical Physics, ISSN: 1463-9076, Vol: 16, Issue: 4, Page: 1469-1478
2014
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LiFePO/C microrods consisting of building blocks of interconnected nanoparticles surrounded by a thin and amorphous coating of carbon have been prepared by a customized hydrothermal method. Appreciable discharge capacity values of 168 mA h g at 0.1 C and 130 mA h g at 5 C rates have been exhibited by the currently synthesized LiFePO/C cathode. The study enumerates the feasibility of exploiting the hydrothermal method to prepare an in situ carbon coated LiFePO /C compound with tunable morphological properties and desirable electrochemical properties observed for up to 100 cycles at a 5 C rate.

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