User-friendly synthesis of highly selective and recyclable mesoporous titanium-silicate catalysts for the clean production of substituted p-benzoquinones
Catalysis Science and Technology, ISSN: 2044-4753, Vol: 4, Issue: 1, Page: 200-207
2014
- 43Citations
- 12Captures
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Article Description
Mesoporous titanium-silicates have been prepared following the evaporation-induced self-assembly (EISA) methodology and characterized by elemental analysis, XRD, N adsorption, SEM, DRS UV-Vis and Raman techniques. The use of acetylacetone during synthesis allowed the formation of highly dispersed dimeric and/or small oligomeric Ti species, within the mesostructured silica network, to be realized. The materials catalyse oxidation of alkylsubstituted phenols to corresponding p-benzoquinones with 100% selectivity using the green oxidant-30% aqueous hydrogen peroxide. The titanium-silicates prepared by the convenient and versatile EISA-based procedure reveal the true heterogeneous nature of the catalysis and do not suffer from titanium leaching. They show advantages over other types of mesoporous Ti,Si-catalysts, such as TiO-SiO mixed oxides and grafted Ti/SiO, in terms of the catalyst stability and reusability. © 2014 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84890078465&origin=inward; http://dx.doi.org/10.1039/c3cy00615h; http://xlink.rsc.org/?DOI=C3CY00615H; http://pubs.rsc.org/en/content/articlepdf/2014/CY/C3CY00615H; https://xlink.rsc.org/?DOI=C3CY00615H; https://dx.doi.org/10.1039/c3cy00615h; https://pubs.rsc.org/en/content/articlelanding/2014/cy/c3cy00615h
Royal Society of Chemistry (RSC)
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