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Supramolecular lanthanide metallogrids exhibiting field-induced single-ion magnetic behavior

Dalton Transactions, ISSN: 1477-9226, Vol: 42, Issue: 13, Page: 4369-4372
2013
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Article Description

A supramolecular strategy has been applied to construct two tetranuclear lanthanide complexes for investigating the magnetic properties of individual lanthanide ions. The Ln complexes (Ln = Dy, Tb) display field-induced slow magnetization relaxation, typical of single-molecule magnet behavior. The four lanthanide ions in the molecules are well separated by distances of ca. 9 Å, and thus the slow magnetization relaxation should be assigned to single-ion magnet (SIM) behavior. Therefore, the present complexes are novel supramolecular aggregates of four isolated SIMs. © The Royal Society of Chemistry 2013.

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