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A molybdenum based metallomicellar catalyst for controlled and selective sulfoxidation reactions in aqueous medium

Green Chemistry, ISSN: 1463-9270, Vol: 16, Issue: 4, Page: 2190-2196
2014
  • 63
    Citations
  • 0
    Usage
  • 17
    Captures
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Metrics Details

  • Citations
    63
    • Citation Indexes
      63
  • Captures
    17

Article Description

A surfactant based molybdenum system that exhibits catalytic activity for sulfoxidation reactions of various organic sulfides in aqueous medium has been developed and comprehensively characterized using IR, XRD, NMR, ESI-MS, DLS and TEM. The catalyst showcases remarkable selectivity for the preparation of both sulfoxides and sulfones in the range of good to excellent yields. Furthermore, the catalyst showed a high degree of tolerance towards various sensitive functional groups such as hydroxyl, acetal, aldehyde, amine, imine, oxime, cyano and alkene. © the Partner Organisations 2014.

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