Palladium(ii) complexes with planar chiral ferrocenyl phosphane-(benz) imidazol-2-ylidene ligands
New Journal of Chemistry, ISSN: 1369-9261, Vol: 38, Issue: 1, Page: 338-347
2014
- 41Citations
- 16Captures
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Article Description
We describe here the first examples of planar chiral ferrocenyl phosphane-benzimidazol-2-ylidene ligands and their coordination chemistry with palladium(ii). All ligand precursors, namely enantiopure ferrocenyl phosphane-(benz)imidazolium salts, and all enantiopure palladium complexes have been fully characterised by H, P and C NMR, mass spectrometry and X-ray diffraction methods for seven examples. The potential of these very bulky bidentate ligands in catalysis was evaluated and compared to their imidazol-2-ylidene analogues. The influence of sterics was shown to be non-negligible as the bulkiest ligand gave the lowest activities in the asymmetric Suzuki-Miyaura reaction. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2014.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84890290458&origin=inward; http://dx.doi.org/10.1039/c3nj00863k; http://xlink.rsc.org/?DOI=C3NJ00863K; http://pubs.rsc.org/en/content/articlepdf/2014/NJ/C3NJ00863K; https://xlink.rsc.org/?DOI=C3NJ00863K; https://dx.doi.org/10.1039/c3nj00863k; https://pubs.rsc.org/en/content/articlelanding/2014/nj/c3nj00863k
Royal Society of Chemistry (RSC)
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