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Chemoselective fragment condensation between peptide and peptidomimetic oligomers

Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 11, Issue: 25, Page: 4142-4146
2013
  • 16
    Citations
  • 0
    Usage
  • 25
    Captures
  • 0
    Mentions
  • 30
    Social Media
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Metrics Details

  • Citations
    16
  • Captures
    25
  • Social Media
    30
    • Shares, Likes & Comments
      30
      • Facebook
        30

Article Description

We report the first example of chemoselective fragment condensation, through native amide bond formation, between peptoid and peptide oligomers. Peptoid oligomers bearing C-terminal salicylaldehyde esters were synthesized and ligated to peptides containing N-terminal serine or threonine residues. We investigate the ligation efficiency of peptoid oligomers varying in length, sequence, and C-terminal steric bulk. These protocols enhance accessibility of structurally complex peptoid-peptide hybrids and will facilitate the design new semi-synthetic proteins with unique attributes. © 2013 The Royal Society of Chemistry.

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