Threefold and chemoselective couplings of triarylbismuths with benzylic chlorides and iodides using palladium catalysis
RSC Advances, ISSN: 2046-2069, Vol: 4, Issue: 25, Page: 13134-13144
2014
- 21Citations
- 6Captures
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Article Description
This paper describes the palladium-catalyzed studies on threefold coupling of triarylbismuth reagents with benzylic chlorides and iodides. The optimized protocol conditions are operationally simple, delivering threefold coupling of a variety of triarylbismuths in combination with benzylic chlorides and iodides. The two optimized protocols allowed the synthesis of a diverse range of unsymmetrical diarylmethanes in an efficient manner. As part of this study, chemoselective transformation of benzylic chlorides and iodides was also achieved. This journal is © the Partner Organisations 2014.
Bibliographic Details
Royal Society of Chemistry (RSC)
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