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Pd-Catalyzed kinetic resolution of cyclic enol ethers. An enantioselective route to functionalised pyrans

Chemical Communications, ISSN: 1364-548X, Vol: 50, Issue: 21, Page: 2735-2737
2014
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Functionalised cyclic enol ethers can be recovered with high levels of enantiocontrol after an asymmetric catalytic [1,3]-rearrangement reaction. These compounds can be further elaborated to a series of carbo- and heterocyclic products in good yield and with excellent levels of stereocontrol. © 2014 The Royal Society of Chemistry.

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