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Electrocatalytic O reduction by a monolayer of hemin: The role of pK of distal and proximal oxygen of a Fe-OOH species in determining reactivity

Chemical Communications, ISSN: 1364-548X, Vol: 50, Issue: 82, Page: 12304-12307
2014
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Investigation of the proton coupled electron transfer steps involved in electrocatalytic ORR by hemin modified electrodes allows the determination of pKs of the proximal and distal oxygen atoms of a rate determining Fe-OOH species. © 2014 The Partner Organisations.

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