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Selective oxidations of activated alcohols in water at room temperature

Chemical Communications, ISSN: 1364-548X, Vol: 50, Issue: 77, Page: 11378-11381
2014
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Article Description

Allylic and benzylic alcohols can be selectively oxidized to their corresponding aldehydes or ketones in water containing nanoreactors composed of the designer surfactant TPGS-750-M. The oxidation relies on catalytic amounts of CuBr, bpy, and TEMPO, with N-methyl-imidazole; air is the stoichiometric oxidant. © Partner Organisations 2014.

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