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Non-covalent sp carbon bonding with ArCF is analogous to CH-π interactions

Chemical Communications, ISSN: 1364-548X, Vol: 50, Issue: 84, Page: 12626-12629
2014
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A combined CSD and ab initio study reveals that the interaction between the sp C-atom in para-substituted ArCF and electron rich atoms is weak (<5 kcal mol), somewhat directional, and thus comparable to CH-π interactions. © 2014 Royal Society of Chemistry.

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