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NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes

Chemical Communications, ISSN: 1364-548X, Vol: 50, Issue: 99, Page: 15730-15732
2014
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We have demonstrated that NBS is able to promote the oxidation of fullerene monoradicals to form 1,4-difunctional fullerenes. The singly bonded fullerene dimers were used as fullerene monoradical precursors, which produced various 1,4-fullerenes with a wide range of functional groups in good to high yields with high regioselectivity in terms of cosolvents and nucleophiles. © The Royal Society of Chemistry 2014.

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