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A palladium NNC-pincer complex: An efficient catalyst for allylic arylation at parts per billion levels

Chemical Communications, ISSN: 1364-548X, Vol: 51, Issue: 18, Page: 3886-3888
2015
  • 38
    Citations
  • 0
    Usage
  • 20
    Captures
  • 0
    Mentions
  • 22
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    38
  • Captures
    20
  • Social Media
    22
    • Shares, Likes & Comments
      22
      • Facebook
        22

Article Description

Allylic arylation of allylic acetates by sodium tetraarylborates in the presence of ppb to ppm (molar) loadings of a palladium NNC-pincer complex catalyst in methanol at 50°C gave the corresponding arylated products in excellent yields. Total turnover numbers of up to 500 000 000 and turnover frequencies of up to 11 250 000 h were achieved.

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