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Chirality sensing and size recognition of N-Boc-amino acids by cage-type dimeric lanthanide complexes: Chirality detection of N-Boc-aspartate anions via luminescence colour change

Chemical Communications, ISSN: 1364-548X, Vol: 51, Issue: 18, Page: 3808-3811
2015
  • 28
    Citations
  • 0
    Usage
  • 24
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    28
    • Citation Indexes
      28
  • Captures
    24

Article Description

Chiral luminescent lanthanide complexes, characterized by covalently-linked face-to-face octadentate cyclen (tetraaza-12-crown-4) ligands, specifically bound a chiral N-Boc-aspartate among various N-Boc amino acid anions to enhance Eu(iii) luminescence intensity at 615 nm. The combination of Tb(iii) and Eu(iii) complexes enabled naked-eye discrimination of N-Boc-d- and l-aspartates via the luminescence colour change.

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