Conformational steering in dicarboxy acids: The native structure of succinic acid
Physical Chemistry Chemical Physics, ISSN: 1463-9076, Vol: 17, Issue: 30, Page: 19726-19734
2015
- 10Citations
- 29Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations10
- Citation Indexes10
- 10
- CrossRef9
- Captures29
- Readers29
- 29
Article Description
Succinic acid, a dicarboxylic acid molecule, has been investigated spectroscopically with computational support to elucidate the complex aspects of its conformational composition. Due to the torsional freedom of the carbon backbone and hydroxy groups, a large number of potentially plausible conformers can be generated with an indication that the gauche conformer is favored over the trans form. The microwave and millimeter wave spectra have been analyzed and accurate spectroscopic constants have been derived that correlate best with those of the lowest energy gauche conformer. For an unambiguous conformational identification measurements were extended to the monosubstituted isotopologues, precisely determining the structural properties. Besides bond distances and angles, particularly the dihedral angle has been determined to be 67.76(11)°, confirming the anomalous tendency of the methylene units to favor gauche conformers when a short aliphatic segment is placed between two carbonyl groups.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84937805169&origin=inward; http://dx.doi.org/10.1039/c4cp05905k; http://www.ncbi.nlm.nih.gov/pubmed/25767836; http://xlink.rsc.org/?DOI=C4CP05905K; http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP05905K; https://xlink.rsc.org/?DOI=C4CP05905K; https://dx.doi.org/10.1039/c4cp05905k; https://pubs.rsc.org/en/content/articlelanding/2015/cp/c4cp05905k
Royal Society of Chemistry (RSC)
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