Versatile reactivity of a rhodium(i) boryl complex towards ketones and imines
Dalton Transactions, ISSN: 1477-9234, Vol: 43, Issue: 18, Page: 6786-6801
2014
- 28Citations
- 17Captures
Metric Options: Counts1 Year3 YearSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations28
- Citation Indexes28
- CrossRef28
- 27
- Captures17
- Readers17
- 17
Article Description
The rhodium(i) boryl complex [Rh(Bpin)(PEt)] (1) reacts with the ketones α,α,α-trifluoroacetophenone and 9-fluorenone by insertion of the CO bond to give [Rh{η-C(CF )(OBpin)CH}(PEt)] (4) and [Rh{η-CH(OBpin)}(PEt )] (6), whereas the reaction with acetophenone leads to the formation of [Rh(H)(PEt)] (2), [Rh(OBpin)(PEt )] (3) and (E)-(Ph)CHCHBpin. Treatment of 1 with ketimines generates [Rh{η-CHC(Ph)N(Ph) (Bpin)}(PEt)] (7), [Rh{(η-C H)N(Ph)(Bpin)}(PEt)] (8) or [Rh{CPhN(H)(Bpin)}(PEt)] (9). The insertion of aldimines into the Rh-B bond gives access to [Rh[η- CH{N(CH)Bpin}CH](PEt )] (11) or [Rh[η-CH{N(Ph)Bpin}C H](PEt)] (12). The latter is converted into the C-H activation product [Rh{(CH )-o-N(Bpin)(CHPh)}(PEt)] (13). Complex 13 reacts with Bpin to yield the boryl complex 1 and the amine PhCHN(Bpin)(CH-o-Bpin). This journal is © the Partner Organisations 2014.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84898025271&origin=inward; http://dx.doi.org/10.1039/c4dt00080c; http://www.ncbi.nlm.nih.gov/pubmed/24647920; https://xlink.rsc.org/?DOI=c4dt00080c; https://dx.doi.org/10.1039/c4dt00080c; https://pubs.rsc.org/en/content/articlelanding/2014/dt/c4dt00080c
Royal Society of Chemistry (RSC)
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know