Multiple coupling of silanes with imido complexes of Mo
Dalton Transactions, ISSN: 1477-9234, Vol: 43, Issue: 22, Page: 8446-8453
2014
- 5Citations
- 7Captures
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Article Description
The bis(imido) complexes (BuN)Mo(PMe )(L) (L = PMe, CH) react with up to three equivalents of silane PhSiH to give the imido-bridged disilyl silyl Mo(vi) complex (BuN){μ-BuN(SiHPh) }Mo(H)(SiHPh)(PMe) (3) studied by NMR, IR and X-ray diffraction. NMR data supported by DFT calculations show that complex 3 is an unusual example of a silyl hydride of Mo(vi), without significant Si⋯H interaction. Mechanistic NMR studies revealed that silane addition proceeds in a stepwise manner via a series of Si-H⋯M agostic and silanimine complexes whose structures were further elucidated by DFT calculations. © the Partner Organisations 2014.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84900550946&origin=inward; http://dx.doi.org/10.1039/c4dt00154k; http://www.ncbi.nlm.nih.gov/pubmed/24740303; http://xlink.rsc.org/?DOI=C4DT00154K; http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00154K; https://xlink.rsc.org/?DOI=C4DT00154K; https://dx.doi.org/10.1039/c4dt00154k; https://pubs.rsc.org/en/content/articlelanding/2014/dt/c4dt00154k
Royal Society of Chemistry (RSC)
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