Highly emissive copper(i) complexes bearing diimine and bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane
Dalton Transactions, ISSN: 1477-9234, Vol: 44, Issue: 1, Page: 411-418
2015
- 48Citations
- 44Captures
Metric Options: Counts1 Year3 YearSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations48
- Citation Indexes48
- 48
- CrossRef46
- Captures44
- Readers44
- 44
Article Description
A highly emissive copper(i) complex bearing (4R,5R)-(-)-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane (diop) and 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (dmpp), [Cu(dmpp)(diop)]PF (1·PF), was newly synthesized. The quantum yield of the luminescence of 1·PF in degassed dichloromethane is 0.38, which is one of the highest values among all copper(i) complexes bearing two bidentate ligands, diimine and diphosphine, under the same conditions. The long lifetime (26 μs) and high intensity of the emission come from the small non-radiative decay rate of the excited states. The TD-DFT study indicates that the charge transfer transition from both copper and diphosphine to diimine orbitals plays an important role in the photophysical properties. Photophysics of [Cu(dmp)(diop)]PF (2·PF, dmp = 2,9-dimethyl-1,10-phenanthroline) was also studied in order to reveal the effects of the introduction of the phenyl group at 4- and 7-positions of phenanthroline. This journal is
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84915788345&origin=inward; http://dx.doi.org/10.1039/c4dt03176h; http://www.ncbi.nlm.nih.gov/pubmed/25375089; http://xlink.rsc.org/?DOI=C4DT03176H; http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03176H; https://xlink.rsc.org/?DOI=C4DT03176H; https://dx.doi.org/10.1039/c4dt03176h; https://pubs.rsc.org/en/content/articlelanding/2015/dt/c4dt03176h
Royal Society of Chemistry (RSC)
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know