T-BuXPhos: A highly efficient ligand for Buchwald-Hartwig coupling in water
Green Chemistry, ISSN: 1463-9270, Vol: 16, Issue: 9, Page: 4170-4178
2014
- 61Citations
- 72Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
An efficient and versatile 'green' catalytic system for the Buchwald-Hartwig cross-coupling reaction in water is reported. In an aqueous micellar medium, the combination of t-BuXPhos with [(cinnamyl)PdCl] showed excellent performance for coupling arylbromides or chlorides with a large set of amines, amides, ureas and carbamates. The method is functional-group tolerant, proceeds smoothly (30 to 50 °C) and provides rapid access to the target compounds in good to excellent isolated yields. When applied to the synthesis of a known NaV1.8 modulator, this method led to a significant improvement of the E-factor in comparison with classical organic synthesis. © the Partner Organisations 2014.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84906243724&origin=inward; http://dx.doi.org/10.1039/c4gc00853g; https://xlink.rsc.org/?DOI=C4GC00853G; http://xlink.rsc.org/?DOI=C4GC00853G; http://pubs.rsc.org/en/content/articlepdf/2014/GC/C4GC00853G; https://dx.doi.org/10.1039/c4gc00853g; https://pubs.rsc.org/en/content/articlelanding/2014/gc/c4gc00853g
Royal Society of Chemistry (RSC)
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