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Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 12, Issue: 40, Page: 7927-7931
2014
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Article Description

Synthesis of a series of iridium(i) complexes of the type [(COD)Ir(IMes)(PPh)]X (X = BF, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.

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