Demonstration of efficient electrochemical biogas reforming in a solid oxide electrolyser with titanate cathode
RSC Advances, ISSN: 2046-2069, Vol: 4, Issue: 72, Page: 38474-38483
2014
- 12Citations
- 30Captures
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Article Description
Biogas reforming is a renewable and promising way to produce syngas. In this work, we demonstrate a novel strategy to directly and electrochemically convert CH-CO into H-CO. Electrochemical reforming of dry CH-CO (1 : 1) mixture is successfully achieved in a 10 μm-thick titanate cathode with oxygen byproduct generated in anode in an oxide-ion-conducting solid oxide electrolyser under external voltages. In addition, loading iron nanocatalyst in titanate cathode or/and increasing applied voltages has further improved CH-CO conversion. The highest methane conversion of approximately 80% is demonstrated for direct electrochemical reforming in cathode in contrast to the low conversion under open circuit condition in oxide-ion-conducting solid oxide electrolyser cathode. © the Partner Organisations 2014.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84906861895&origin=inward; http://dx.doi.org/10.1039/c4ra05587j; https://xlink.rsc.org/?DOI=C4RA05587J; http://xlink.rsc.org/?DOI=C4RA05587J; http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA05587J; https://dx.doi.org/10.1039/c4ra05587j; https://pubs.rsc.org/en/content/articlelanding/2014/ra/c4ra05587j
Royal Society of Chemistry (RSC)
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