Electrochemical luminescence modulation in a Eu(iii) complex-modified TiO electrode
Journal of Materials Chemistry C, ISSN: 2050-7526, Vol: 3, Issue: 27, Page: 7135-7142
2015
- 30Citations
- 16Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
Electrochemical modulation of red luminescence from a europium(iii) complex has been demonstrated. In order to elucidate the mechanism of luminescence modulation, its cyclic voltammogram, absorption spectra, emission spectra, emission lifetime, and emission quantum yield were measured. From these measurements, the modulation of emission was found to be achieved through an electrochemical reaction of TiO, which is facilitated by electron transfer between the europium(iii) complex and TiO. Subsequent immobilization of the europium(iii) complex on a TiO electrode resulted in an on-off emission contrast of 74:1, with the response time and repetition stability of the emission switching being considerably improved.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84936882249&origin=inward; http://dx.doi.org/10.1039/c4tc02996h; https://xlink.rsc.org/?DOI=C4TC02996H; http://xlink.rsc.org/?DOI=C4TC02996H; http://pubs.rsc.org/en/content/articlepdf/2015/TC/C4TC02996H; https://dx.doi.org/10.1039/c4tc02996h; https://pubs.rsc.org/en/content/articlelanding/2015/tc/c4tc02996h
Royal Society of Chemistry (RSC)
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