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Synthesis, molecular and electronic structure, and reactions of a Zn-Hg-Zn bonded complex

Chemical Communications, ISSN: 1364-548X, Vol: 51, Issue: 26, Page: 5743-5746
2015
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Reaction of (NacNac)ZnI with potassium/mercury amalgam gave the trimetallic compound {(NacNac)Zn}Hg (1) containing a Zn-Hg-Zn unit and the first example of a bond between two different Group 12 metals; DFT and QTAIM analyses suggest that 1 is best described as two formally Zn(i) atoms with a Hg(0) atom positioned between them; reactions of 1 with stoichiometric I, FpI or Fp gave addition products of the type (NacNac)ZnX (X = I, Fp) and Hg. NacNac = HC{C(Me)N(2,6-CHPr)}; Fp = CpFe(CO). This journal is

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