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On Zn(ii) 2,2′-bisdipyrrin circular helicates

Chemical Communications, ISSN: 1364-548X, Vol: 51, Issue: 27, Page: 5906-5909
2015
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Article Description

Coordination of two 2,2′-bisdipyrrin ligands, bearing methyl ester or methylthioether peripheral groups, with Zn(ii) cations leads not only to the formation of the expected linear helicates but also concomitantly to novel tri- and tetra-nuclear circular species that have been isolated and fully characterized in solution and by X-ray diffraction.

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