Cobalt(II)/silver relay catalytic isocyanide insertion/cycloaddition cascades: A new access to pyrrolo[2,3-b]indoles
Chemical Communications, ISSN: 1364-548X, Vol: 51, Issue: 46, Page: 9519-9522
2015
- 83Citations
- 14Captures
- 1Mentions
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Metrics Details
- Citations83
- Citation Indexes83
- 83
- CrossRef81
- Captures14
- Readers14
- 14
- Mentions1
- News Mentions1
- News1
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Cobalt(II)/silver relay catalytic isocyanide insertion/cycloaddition cascades: a new access to pyrrolo[2,3-b]indoles.
Authors: Qian Gao, Peng Zhou, Feng Liu, Wen-Juan Hao, Changsheng Yao, Bo Jiang, Shu-Jiang Tu PMID: 25967928 DOI: 10.1039/c5cc02754c Publication Type: Research Support, Non-U.S. Gov’t
Article Description
The combination of Co(acac) and AgOTf enables the bimetallic relay catalysis reaction of 2-ethynylanilines and isocyanides, allowing easy and low-cost access to new densely functionalized pyrrolo[2,3-b]indoles. The reaction pathway involves a Co(acac)-catalyzed double isocyanide insertion followed by a silver-enabled 1,3-dipolar cycloaddition. The synthetic utility of these bicycloaddition reactions results in subsequent C-C and C-N bond-forming events to rapidly build up molecular complexity.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84930226582&origin=inward; http://dx.doi.org/10.1039/c5cc02754c; http://www.ncbi.nlm.nih.gov/pubmed/25967928; https://xlink.rsc.org/?DOI=C5CC02754C; http://xlink.rsc.org/?DOI=C5CC02754C; http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC02754C; https://dx.doi.org/10.1039/c5cc02754c; https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc02754c
Royal Society of Chemistry (RSC)
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