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The reactions of TiCl, and of UF with TiCl in liquid ammonia: Unusual coordination spheres in [Ti(NH)]Cl·6NH and [UF(NH)]Cl·3.5NH

Chemical Communications, ISSN: 1364-548X, Vol: 51, Issue: 59, Page: 11826-11829
2015
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TiCl and NH form octaammine titanium(iii) chloride ammonia (1/6), [Ti(NH)]Cl·6NH, which is the first structurally characterized octaammine complex of a transition metal. An excess of TiCl reacts with UF in liquid NH and forms octaammine fluorido uranium(iv) chloride ammonia (1/3.5), [UF(NH)]Cl·3.5NH. It shows a distorted threefold-capped trigonal-prismatic coordination sphere around U(iv).

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