The reactions of TiCl, and of UF with TiCl in liquid ammonia: Unusual coordination spheres in [Ti(NH)]Cl·6NH and [UF(NH)]Cl·3.5NH
Chemical Communications, ISSN: 1364-548X, Vol: 51, Issue: 59, Page: 11826-11829
2015
- 11Citations
- 16Captures
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Article Description
TiCl and NH form octaammine titanium(iii) chloride ammonia (1/6), [Ti(NH)]Cl·6NH, which is the first structurally characterized octaammine complex of a transition metal. An excess of TiCl reacts with UF in liquid NH and forms octaammine fluorido uranium(iv) chloride ammonia (1/3.5), [UF(NH)]Cl·3.5NH. It shows a distorted threefold-capped trigonal-prismatic coordination sphere around U(iv).
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84936971395&origin=inward; http://dx.doi.org/10.1039/c5cc04411a; http://www.ncbi.nlm.nih.gov/pubmed/26109184; http://xlink.rsc.org/?DOI=C5CC04411A; http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04411A; https://xlink.rsc.org/?DOI=C5CC04411A; https://dx.doi.org/10.1039/c5cc04411a; https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc04411a
Royal Society of Chemistry (RSC)
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