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Facilitated carbon dioxide reduction using a Zn(II) complex

Chemical Communications, ISSN: 1364-548X, Vol: 52, Issue: 8, Page: 1685-1688
2016
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Two new Zn(ii) complexes have been prepared and evaluated for their capacity to activate and reduce CO. The electrochemical properties of dichloro[phenyldi(2-pyridyl)phosphine-κ-N,N′]zinc(ii) 1 and dichloro[diphenyl-(2-pyridyl)phosphine-κ-N]zinc(ii) 2 are compared using cyclic voltammetry. Electrochemical results indicate that 2 leads to a facilitated CO reduction to evolve CO at a glassy carbon electrode.

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