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Photochemical water oxidation by cyclometalated iridium(iii) complexes: A mechanistic insight

Chemical Communications, ISSN: 1364-548X, Vol: 52, Issue: 19, Page: 3840-3843
2016
  • 10
    Citations
  • 0
    Usage
  • 22
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    10
    • Citation Indexes
      10
  • Captures
    22

Article Description

The proficiency of the cyclometalated iridium complexes [(η-CMe)IrCl(L1)] (1), [(η-CMe)IrCl(L2)] (2) and [(η-CMe)IrCl(L3)] (3) has been examined towards photochemical water oxidation. The involvement of Ir(iv/v) in the catalytic process has been explored via CV, UV/vis, XPS spectroscopic studies and appreciable TON relative to the theoretical value of 1 from GC.

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