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Probing the coordination environment of Ti ions coordinated to nitrogen-containing Lewis bases

Physical Chemistry Chemical Physics, ISSN: 1463-9076, Vol: 17, Issue: 32, Page: 20853-20860
2015
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Article Description

Multi-frequency continuous-wave and pulsed EPR techniques are employed to investigate the coordination of nitrogen-containing ligands to Ti-chloro complexes. Frozen solutions of TiCl and TiCl(Py) dissolved in nitrogen-containing solvents have been investigated together with the TiCl(Py) solid-state complex. For these different systems, the hyperfine and nuclear quadrupole data of Ti-bound N nuclei are reported and discussed in the light of DFT computations, allowing for a detailed description of the microscopic structure of these systems.

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